The Rydberg equation is
1/λ = RZ2(1/n12 - 1/n22)
where λ is the wavelength of the photon emitted
R is the Rydberg constant
Z is the atomic number which in this case is 1 since we are dealing with the hydrogen atom
n1 is the same as m which is 8
n2 is 12
So we work out the wavelength of the emitted photon as follows:
1/λ = 1.097 x 10^7 (1/8^2 - 1/12^2)
1/λ = 1.097 x 10^7 x 0.00868
1/λ =9.522 x 10^4 m^-1
λ= 1.050 x 10^-5m
We then use f= c/λ to calculate the frequency
f = 3.00 x 10^8/1.050 x 10^-5
f = 2.86 x 10^13 Hz
The wavelength and frequency that we just found tell us that the transition emits energy in the infra-red region of the electromagnetic spectrum. So one would not expect to see a spectral line for a transition from m =8 to m = 12
No comments:
Post a Comment